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## Page 1

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- Safety data sheet according to 1907/2006/EC, Article 31
Printing date 28.03.2012      Version: 2 (GB)      Revision: 28.03.2012

1 Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name: Diamant Hartgipsplatte
1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the preparation: Gypsum board
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Knauf Gips KG
Postfach 10
97343 Iphofen
Germany
Tel +49 (0)9323/31-0
Fax +49 (0)9323/31-277

Further information obtainable from:
Technical information service
Tel +49 (0)9001/31-1000 (see point 16)
E-mail Knauf-Direkt@ Knauf.de

1.4 Emergency telephone number:
Hotline for symptoms of poisoning and embryonic toxicology, Berlin
Tel +49 (0)30-19240

2 Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.
Information concerning particular hazards for human and environment:
No hazards to be particularly mentioned.

2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 Void
Hazard pictograms Void
Signal word Void
Hazard statements Void

2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

3 Composition/information on ingredients

Chemical characterization: Mixtures
Description:
Fire-resistant board impregnated made of set gypsum, cladded with board. Gypsum core with modest starch additives, tensides, hydrophobizing agents added fibre for strength and fire-resistance reinforcement. Partly mineral additives.

Dangerous components: Void
Further components:
CAS: 7778-18-9 calcium sulfate
EINECS: 231-900-3
Reg.nr.: 01-211944918-26-XXXX
Remark: Materials with a threshold value for exposure in the workplace - see point 8.

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## Page 2

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- Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 28.03.2012 Version: 2 (GB) Revision: 28.03.2012
Trade name: Diamant Hartgipsplatte

4 First aid measures

4.1 Description of first aid measures
General information: No special measures required.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Wash off with water and soap.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:
Rinse out mouth and then drink plenty of water.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures

5.1 Extinguishing media
Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
For safety reasons unsuitable extinguishing agents: None.
5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO₂)
5.3 Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
Additional information The product is not flammable.

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Avoid formation of dust.
6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up: Pick up mechanically.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

7.1 Precautions for safe handling
Prevent formation of dust.
Do not inhale dust.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Store in dry conditions.
Storage class: Storage class in accordance with VCI: 13 (non-combustible solid matter)
7.3 Specific end use(s) No further relevant information available.

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## Page 3

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- Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 28.03.2012 Version: 2 (GB) Revision: 28.03.2012
Trade name: Diamant Hartgipsplatte

8 Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.

8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Remark A = alveolar fraction, E = inhalable fraction
Additional information: The lists valid during the making were used as basis.

8.2 Exposure controls
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Respiratory protection: Wear dust mask FFP1 if dust forms.
Protection of hands: Not required.
Eye protection: Wear safety goggles with side protection if dust develops.
Body protection: Protective work clothing

9 Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Plate
Colour: Gypsum core: white, white-beige, white-grey
Board: blue
Odour: Odourless
Odour threshold: Not determined.
pH-value: Not applicable in the supplied state, suspension 6-9.
Change in condition
Melting point/Melting range: Not applicable.
Boiling point/Boiling range: Not applicable.
Flash point: Not applicable.
Flammability (solid, gaseous): Not applicable.
Ignition temperature:
Decomposition temperature: Not determined.
Self-igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Vapour pressure: Not applicable.
Density at 20°C: ca. 1.05 g/cm³
Relative density Not determined.
Vapour density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
water: c. 2 g/l (calcium sulphate x 2 H2O) at 20°C
Segregation coefficient (n-octanol/water): Not applicable.
Viscosity:
Dynamic: Not applicable.

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## Page 4

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- Page 4/5

Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 28.03.2012 Version: 2 (GB) Revision: 28.03.2012

Trade name: Diamant Hartgipsplatte

Kinematic: Not applicable.
9.2 Other information
Thermal decomposition of gypsum
in CaSO4 and H2O from 14 0 °C
in CaO and SO3 from 1000 °C

* 10 Stability and reactivity

10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Avoid damp conditions.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information

11.1 Information on toxicological effects Not toxic.
Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us.

* 12 Ecological information

12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (appendix 4, VwVwS Deutschland of 17.05.1999): Little risk of pollution
Do not allow product to reach ground water, water course or sewage system.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.

13 Disposal considerations

13.1 Waste treatment methods
Recommendation Disposal must be made according to official regulations.
European waste catalogue
17 08 02 gypsum-based construction materials other than those mentioned in 17 08 01
17 09 04 mixed construction and demolition wastes other than those mentioned in 17 09 01, 17 09 02 and 17 09 03

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## Page 5

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- Safety data sheet according to 1907/2006/EC, Article 31
Printing date 28.03.2012 Version: 2 (GB) Revision: 28.03.2012

Trade name: Diamant Hartgipsplatte

Uncleaned packaging: Recommendation: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.

14 Transport information
14.1 UN-Number ADR, IMDG, IATA Void
14.2 UN proper shipping name ADR, IMDG, IATA Void
14.3 Transport hazard class(es) ADR, IMDG, IATA Class Void
14.4 Packing group ADR, IMDG, IATA Void
14.5 Environmental hazards: Marine pollutant: No
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: -

15 Regulatory information
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

Building material class: Particulars see technical data sheet.
Department issuing MSDS: Knauf Gips KG, Abteilung Umwelt und Sicherheit, 97343 Iphofen
Contact: Technical information service (see point 1) A call to Knauf Direkt will be charged at 0.39 € per minute. Callers, the telephone numbers of whom are not saved in the Knauf Gips KG address database, e.g. private property owners or non-customers, will pay 1.69 € per minute from the German network. Callers using mobile telephones will be charged according to the network provider and tariff.

Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals

* Data compared to the previous version altered.

